Hot bitumen used in roofing and surfacing gives off fume and presents a serious burn risk. It is a hazard for roofers and surfacing gangs, particularly with torch-on and boiler work.
Controls should be applied in order — eliminate or substitute first, then engineering controls, then PPE as the last line.
Yes — heating bitumen produces fume that is hazardous to health, and the work also carries a serious burn and fire risk. A COSHH assessment covers the fume controls, and a hot-works permit covers the fire risk.
Keep the temperature to the minimum needed and never overheat, work upwind and position people away from the plume, ventilate enclosed areas, and use RPE where fume cannot otherwise be controlled.
Complys writes a bitumen & hot works COSHH assessment tailored to how you actually use it, in minutes — COSHH 2002 compliant, editable, with review-date tracking. Your first is free.